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71.
The development of biomass-derived nitrogen-doped porous carbons (NPCs) for the oxygen reduction reaction (ORR) is important for sustainable energy systems. Herein, NPCs derived from Astragali Radix (AR) via a cost-effective strategy are reported for the first time. The as-prepared AR-950-5 catalyst shows a stacked layer-like structure and porosity. Notably, the optimized AR-950-5 delivers catalytic activity comparable to that of commercial Pt/C (C-Pt/C), with high onset potential, positive half-wave potential and large limiting current density. It also displays superior long-term stability and methanol tolerance for ORR. This work will pave the way for a new approach in the development of highly active and low-cost NPCs for fuel cells.  相似文献   
72.
73.
We consider ex post demand information sharing in a two-echelon supply chain in which two suppliers sell differentiated products through a common retailer. We model three scenarios of information sharing to characterise the conditions under which information sharing may benefit or hurt different players: (1) no supplier is informed; (2) only one supplier is informed; and (3) both suppliers are informed. We find that the retailer may voluntarily share the low demand information when the product differentiation and demand magnitude satisfy certain conditions. In contrast, the retailer has no incentive to share the high demand information, even though this information benefits the suppliers. To achieve information sharing, we propose a side payment mechanism, which allows benefitted players to subsidise hurtful players. Finally, we extend our model by considering a situation where the suppliers have limited capacity and may invest to ramp up production capacity to satisfy a high demand.  相似文献   
74.
Wireless Personal Communications - In this paper, we first briefly explain why mobile network computers should be used as mobile terminals based on the concept of mobile network computer and cloud...  相似文献   
75.
The use of oxidoreductases (EC1) in non-conventional reaction media has been increasingly explored. In particular, deep eutectic solvents (DESs) have emerged as a novel class of solvents. Herein, an in-depth study of bioreduction with an alcohol dehydrogenase (ADH) in the DES glyceline is presented. The activity and stability of ADH in mixtures of glyceline/water with varying water contents were measured. Furthermore, the thermodynamic water activity and viscosity of mixtures of glyceline/water have been determined. For a better understanding of the observations, molecular dynamics simulations were performed to quantify the molecular flexibility, hydration layer, and intraprotein hydrogen bonds of ADH. The behavior of the enzyme in DESs follows the classic dependence of water activity (aW) in non-conventional media. At low aW values (<0.2), ADH does not show any activity; at higher aW values, the activity was still lower than that in pure water due to the high viscosities of the DES. These findings could be further explained by increased enzyme flexibility with increasing water content.  相似文献   
76.
SrLa[Ga1−x(R0.5Ti0.5)x]O4 (R = Mg, Zn) ceramics were prepared by a standard solid state sintering method. The single-phase ceramics with K2NiF4-type layered perovskite structure and I4/mmm space group were obtained, indicating that SrLa(R0.5Ti0.5) and SrLaGaO4 can form the unlimited solid solutions. With increasing x for = Mg and Zn, εr increases monotonously, the Qf value first increases and then decreases, while τf increases from a negative to a positive value. The optimized microwave dielectric properties were obtained as following: εr = 23.3, Qf = 89 400 GHz, τf = −0.8 ppm/°C for SrLa[Ga0.6(Mg0.5Ti0.5)0.4]O4 and εr = 23.3, Qf = 76 200 GHz, τf = 0.2 ppm/°C for SrLa[Ga0.7(Zn0.5Ti0.5)0.3]O4, indicating that the present solid solution ceramics are the promising candidates as microwave resonator materials for the telecommunication applications.  相似文献   
77.
综采工作面在推进过程中经常会受到断层的影响,严重制约了矿井的安全生产及经济效益。以寺河煤矿西井区W2303工作面采用留顶煤、割底矸等手段过逆断层群为工程实例,分析了综采工作面安全、快速过逆断层群技术的应用效果,对于类似矿山也有一定的借鉴价值。  相似文献   
78.
综述了有色金属工业砷污染物的来源及其无害化处理的方法,分析了包封固砷(水泥固化和玻璃固化)和矿物固砷(钙盐、铝盐、镁盐、硫化沉淀法)的优缺点和局限性,重点对将砷以臭葱石形式进行安全处理的合成方法和浸出稳定性的研究现状进行阐述。分析表明,晶态臭葱石合成是将砷以臭葱石形式进行安全处置的基础,稳定性是关键,进一步降低溶液过饱和度以实现大尺寸、高稳定性臭葱石的合成是发展方向。  相似文献   
79.
With the depletion of fossil fuels and the aggravation of environmental pollution, the research and development speed of electric vehicles has been accelerating, and the thermal management of battery pack has become increasingly important. This paper selects the electric vehicle battery pack with natural air cooling as the study subject, conducts simulation analysis of the heat dissipation performance of battery packs with and without vents. Then this paper researches on the influence of internal flow field and external flow field. Field synergy principle is used to analyze the effect of velocity field and temperature field amplitude. The results show the following: it is found that the maximum temperature rise and the internal maximum temperature difference of the battery pack with vents are reduced by about 23.1% and 19.9%, raising speed value can improve the heat dissipation performance, and raising temperature value can decrease the heat dissipation performance. Reasonable design of the vents can make the inner and outer flow field work synergistically to achieve the best cooling effect. Then the reference basis for the air cooling heat dissipation performance analysis of electric vehicle, battery pack structure arrangement, and air‐inlet and air‐outlet pattern choosing are offered.  相似文献   
80.
为准确测定气体裂变产物88Kr的半衰期,本工作从辐照铀靶中分离得到3个放化纯的88Kr气体测量源。以85Kr作内标监督源,137Cs或57Co作外标监督源,使用多个HPGe探测器分别采用单探测器位置接力法和双探测器位置接力法跟踪测量88Kr 196.3 keV能量的特征γ射线,跟踪时间均在8个半衰期以上,以获得其半衰期数据。对3次独立测量数据用多种方法进行处理,最终得到88Kr半衰期测定结果为(2.796±0.015) h。  相似文献   
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